Product ID:CP3810005 ANHYDROUS HYDRAZINE
MSDS Date:01/01/1995
FSC:9135
NIIN:00-149-1610
MSDS Number: BXNWN

OLIN CORP

120 LONG RIDGE RD
STAMFORD, CT 06904-1355
US

Emergency Phone: 203-356-3449

Info Phone: 203-356-3449

Cage: 8X135

OLIN CORPORATION

4500 NORWALK, CT 06856-4500 US

Telephone: 203-750-3000/800-511-MSDS

Cage: 99530

HYDRAZINE

CAS: 302-01-2

RTECS: MU7175000

Fraction By Weight: >99.5%

OSHA PEL 0.1 PPM

ACGIH TLV: 0.1 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 0-0.5%

LD50 LC50 Mixture:ORAL LD50 (RAT): 60 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: FATAL, IRRITATING TO
NOSE/THROAT/UPPER RESPIRATORY TRACT & LUNGS, PULMONARY EDEMA,
LUNG/LIVER/KIDNEY/BLOOD/CNS DAMGE, HEMOLYSIS OF BLOOD CELLS. SKIN:
FATAL IF ABSORBED, SEVERE IRRITATION/B URNS/DERMATITIS/ALLERGIC
REACTION. EYES: HARMFUL/IRRITATION/BURNS/PERMANENT CORNEAL DAMAGE.
INGESTION: FATAL, (SEE SUPP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, INFLAMMATION, BRONCHITIS, VOMITING,
DIARRHEA, NAUSEA, DIZZINESS, CYANOSIS, CONVULSIONS, REDUCTION OF
PACKED CELL VOLUME, RASH, SWELLING, REDNESS, DISCHARGE, TEMPORARY
BLINDNESS, ABDOMINAL PAIN, BLEEDING, TISSUE ULCERATION.
Medical Cond Aggravated by Exposure:LIVER/KIDNEY/BLOOD/CARDIOVASCULAR
DISEASE & ASTHMA.

First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER FOR 15
MINS. INGESTION: IMMEDIATELY DRINK LARGE AMOUNTS OF WATER. INDUCE
VOMITING. DON'T GIVE ANYTHING BY MOUTH IF UNCONSCIOUS/CONVULSIVE.
INHALAT ION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. KEEP
WARM & QUIET. OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point:100F
Lower Limits:4.7
Upper Limits:100
Extinguishing Media:ALCOHOL FOAM, CO2, WATER SPRAY.
Fire Fighting Procedures:USE WATER TO COOL FIRE EXPOSED CONTAINERS.
WEAR A POSITIVE PRESSURE SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:AUTO-IGNITION TEMP: 518F. ABSORPTION OF
ANHYDROUS HYDRAZINE BY RAGS/COTTON WASTE/SIMILIAR ORGANIC MATERIALS
WILL EVENTUALLY RESULT IN SPONTANEOUS COMBUSTION.

Spill Release Procedures:EVACUATE & ISOLATE AREA/REMOVE IGNITION
SOURCES/STOP SOURCE. AIR: SUPPRESS VAPORS W/WATER FOG. CONTAIN FOR
TREATMENT/DISPOSAL. WATER: SAFELY DIVERT WATER FLOW AROUND AREA.
LAND: DIKE/TRENCH/CONTAIN. D ILUTE TO 10% W/WATER & NEUTRALIZE.
(SEESUPP)
Neutralizing Agent:5-8% CALCIUM HYPOCHLORITE SOLUTION.

Handling and Storage Precautions:STORE IN WELL VENTILATED AREA AWAY
FROM IGNITION SOURCES. DON'T STORE >124F, EXPOSE TO DIRECT LIGHT,
CONTAMINATE. MAINTAIN INERT ATMOSPHERE ALWAYS.
Other Precautions:DON'T TAKE INTERNALLY. AVOID CONTACT
W/SKIN/EYES/CLOTHING. ELECTRICALLY GROUND ALL CONTAINERS & HANDLING
EQUIPMENT. RETEST MATERIAL >5 YEARS OLD BEFORE USE. PACKAGE ONLY IN
TEFLON/HIGH DENSITY POLYETH YLENE/304L/347 STAINLESS STEEL.

Respiratory Protection:WEAR A NIOSH/MSHA APPROVED POSITIVE PRESSURE AIR
SUPPLIED RESPIRATOR IF ANY EXPOSURE OCCURS.
Ventilation:LOCAL EXHAUST TO MAINTAIN LEVELS Protective Gloves:BUTYL RUBBER
Eye Protection:SAFETY GLASSES & FACE SHIELD
Other Protective Equipment:BUTYL RUBBER BOOTS/APRON/PROTECTIVE SUIT.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH AFTER HANDLING. RINSE & DISCARD ALL LEATHER PRODUCTS.
Supplemental Safety and Health
PH (1% SOLUTION IN NEUTRAL, DISTILLED WATER): 10.1-10.7. INCOMPATIBLES:
IRON/COPPER/LEAD MANGANESE/MOLYBDENUM. HEALTH CONT'D:
IRRITATION/BURNS TO GI TRACT/STOMACH/INTESTINE. HYDRAZINE IS
CONSIDERED MU TAGENIC. SPILLS: ABSORB NEUTRALIZED MATERIAL
W/CLAY/SAND/COMMERCIAL ABSORBENT. DECONTAMINATE AREA W/DETERGENT &
WATER.

Boiling Pt:B.P. Text:236F
Melt/Freeze Pt:M.P/F.P Text:35F
Decomp Temp:Decomp Text:>482F
Vapor Pres:14.9
Vapor Density:1.1
Spec Gravity:1.004
pH:(SUPP)
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID W/AMMONIA ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS/HYDROGEN PEROXIDE/NITROGEN TETROXIDE/FLUORINE/HALOGEN
FLUORIDES/FUMING NITRIC ACID/METAL OXIDES (SUPP)
Stability Condition to Avoid:TEMPS >124F, DIRECT LIGHT, HEAT, SPARKS,
OPEN FLAME & OTHER IGNITION SOURCES.
Hazardous Decomposition Products:AMMONIA & HYDROGEN.

Waste Disposal Methods:AS HAZARDOUS WASTE, MUST BE DISPOSED OF IN A
PERMITTED HAZARDOUS WASTE TREATMENT/STORAGE & DISPOSAL FACILITY BY
INCINERATION IAW/FEDERAL, STATE & LOCAL REGULATIONS. POISON UN2029

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